A weak acid HX has the dissociation constant M. It forms a salt NaX on reaction with alkali. The per — Ionic Equilibrium Chemistry Question
Question
A weak acid HX has the dissociation constant $1 \times 10^{-5}$ M. It forms a salt NaX on reaction with alkali. The percentage hydrolysis of 0.1 M solution of NaX is
Answer: B
💡 Solution & Explanation
NaX undergoes anionic hydrolysis. The hydrolysis constant $K_h = \frac{K_w}{K_a} = \frac{10^{-14}}{10^{-5}} = 10^{-9}$. The degree of hydrolysis $h = \sqrt{\frac{K_h}{C}} = \sqrt{\frac{10^{-9}}{0.1}} = \sqrt{10^{-8}} = 10^{-4}$. The percentage hydrolysis is $h \times 100\% = 10^{-4} \times 100\% = 10^{-2}\% = 0.01\%$.
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