Ionic EquilibriummediumMCQ SINGLE

How much water must added to 300 ml of solution of for the degree of dissociation of the acid to douIonic Equilibrium Chemistry Question

Question

How much water must added to 300 ml of $0.2\text{ M}$ solution of $\text{CH}_3\text{COOH}$ for the degree of dissociation of the acid to double? $K_a$ for the acetic acid = $1.8 \times 10^{-5}$.

Answer: D

💡 Solution & Explanation

According to Ostwald's dilution law, the degree of dissociation $\alpha \approx \sqrt{\frac{K_a}{C}} \propto \sqrt{V}$. To double the degree of dissociation ($\alpha \to 2\alpha$), the final volume must become 4 times the initial volume. Thus, $V_{final} = 4 \times 300\text{ ml} = 1200\text{ ml}$. The amount of water to be added is $V_{final} - V_{initial} = 1200\text{ ml} - 300\text{ ml} = 900\text{ ml}$.

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