How much water must added to 300 ml of solution of for the degree of dissociation of the acid to dou — Ionic Equilibrium Chemistry Question
Question
How much water must added to 300 ml of $0.2\text{ M}$ solution of $\text{CH}_3\text{COOH}$ for the degree of dissociation of the acid to double? $K_a$ for the acetic acid = $1.8 \times 10^{-5}$.
💡 Solution & Explanation
According to Ostwald's dilution law, the degree of dissociation $\alpha \approx \sqrt{\frac{K_a}{C}} \propto \sqrt{V}$. To double the degree of dissociation ($\alpha \to 2\alpha$), the final volume must become 4 times the initial volume. Thus, $V_{final} = 4 \times 300\text{ ml} = 1200\text{ ml}$. The amount of water to be added is $V_{final} - V_{initial} = 1200\text{ ml} - 300\text{ ml} = 900\text{ ml}$.