Ionic EquilibriummediumMCQ SINGLE

Isohydric solutions are the solutions having the same concentration of hydronium ion. If solution isIonic Equilibrium Chemistry Question

Question

Isohydric solutions are the solutions having the same concentration of hydronium ion. If $0.2\text{ M} – \text{HA}$ solution is isohydric with $4 \times 10^{-4}\text{ M} – \text{HCl}$ solution, then $K_b$ of $\text{A}^-$ is

Answer: B

💡 Solution & Explanation

For the strong acid HCl, $[\text{H}^+] = 4 \times 10^{-4}\text{ M}$. Because HA is isohydric, it also has $[\text{H}^+] = 4 \times 10^{-4}\text{ M}$. The dissociation constant of the weak acid is $K_a = \frac{[\text{H}^+]^2}{C} = \frac{(4 \times 10^{-4})^2}{0.2} = \frac{16 \times 10^{-8}}{0.2} = 8 \times 10^{-7}$. The question asks for the $K_b$ of its conjugate base $\text{A}^-$, which is $K_b = \frac{K_w}{K_a} = \frac{10^{-14}}{8 \times 10^{-7}} = 1.25 \times 10^{-8}$.

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