A quantity of 60 g CH₃COOH and 46 g CH₃CH₂OH reacts in 5 L flask to form 44 g CH₃COOC₂H₅ at equilibr — Chemical Equilibrium Chemistry Question
Question
A quantity of 60 g CH₃COOH and 46 g CH₃CH₂OH reacts in 5 L flask to form 44 g CH₃COOC₂H₅ at equilibrium. On taking 120 g CH₃COOH and 46 g CH₃CH₂OH, CH₃COOC₂H₅ formed at equilibrium is
Answer: D
💡 Solution & Explanation
First case: 1 mol acid + 1 mol alcohol → 0.5 mol ester. K_c = (0.5 × 0.5) / (0.5 × 0.5) = 1. Second case: 2 mol acid + 1 mol alcohol. Let x mol ester form. K_c = x² / ((2-x)(1-x)) = 1. Solving gives x² = x² - 3x + 2, so 3x = 2, x = 2/3 mol. Mass of ester = (2/3) × 88 = 58.67 g. Therefore, correct answer is D.
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