At a certain temperature, the equilibrium constant of the reaction: N₂(g) + O₂(g) ⇌ 2NO(g) is 0.0004 — Chemical Equilibrium Chemistry Question
Question
At a certain temperature, the equilibrium constant of the reaction: N₂(g) + O₂(g) ⇌ 2NO(g) is 0.0004. Assuming air to be a mixture of four volumes of nitrogen with one volume of oxygen, the percentage of nitric oxide, by volume, in the gas produced by allowing air to reach equilibrium at this temperature, is
💡 Solution & Explanation
Let total pressure be P. Initial pressures: P_N₂ ≈ 0.8P, P_O₂ ≈ 0.2P. Assuming small conversion, P_N₂ and P_O₂ stay roughly the same. K_p = P_NO² / (0.8P × 0.2P) = 0.0004. P_NO² = 0.0004 × 0.16P² = 64 × 10⁻⁶ P². Thus, P_NO = 8 × 10⁻³ P = 0.008P. Percentage by volume = (P_NO / P) × 100 = 0.8%. Therefore, correct answer is B.