Two bars of different metals are heated to and then immersed in identical, insulated containers each — Thermodynamics and Thermochemistry Chemistry Question
Question
Two bars of different metals are heated to $60^\circ\text{C}$ and then immersed in identical, insulated containers each containing 200 g of water at $20^\circ\text{C}$. Will the metal with higher or lower atomic mass cause a greater temperature rise in water?
💡 Solution & Explanation
According to the Dulong-Petit law, the molar heat capacity of solid elements is approximately constant ($3R$). Consequently, a metal with a lower atomic mass has a higher specific heat capacity (heat capacity per gram). For equal masses, the lower atomic mass metal holds more heat and thus transfers more heat to the water, causing a greater temperature rise.