Use the following data to calculate the enthalpy of hydration for caesium iodide and caesium hydroxi — Thermodynamics and Thermochemistry Chemistry Question
Question
Use the following data to calculate the enthalpy of hydration for caesium iodide and caesium hydroxide, respectively:<br>Compound: CsI, Lattice energy = +604, $\Delta H_{\text{Solution}} = +33$<br>Compound: CsOH, Lattice energy = +724, $\Delta H_{\text{Solution}} = -72$
Answer: A
💡 Solution & Explanation
The equation relates: $\Delta H_{\text{solution}} = \text{Lattice Energy (LE)} + \Delta H_{\text{hydration}}$. Re-arranging gives $\Delta H_{\text{hydration}} = \Delta H_{\text{solution}} - \text{LE}$. For CsI: $33 - 604 = -571\text{ kJ/mol}$. For CsOH: $-72 - 724 = -796\text{ kJ/mol}$.
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