Thermodynamics and ThermochemistrymediumMCQ SINGLE

A reaction at 300 K with consist of 3 moles of A(g), 6 moles of B(g) and 3 moles of C(g). If A, B anThermodynamics and Thermochemistry Chemistry Question

Question

A reaction at 300 K with $\Delta G^\circ = -1743 \text{ kJ}$ consist of 3 moles of A(g), 6 moles of B(g) and 3 moles of C(g). If A, B and C are in equilibrium in one liter vessel, then the reaction should be ($\ln 2 = 0.7, R = 8.3 \text{ J/K-mol}$)

Answer: C

💡 Solution & Explanation

Equilibrium constant $\ln K_c = -\frac{\Delta G^\circ}{RT} = \frac{1743}{8.3 \times 300} = \frac{1743}{2490} = 0.7 = \ln 2 \implies K_c = 2$. At equilibrium, $[\text{A}]=3, [\text{B}]=6, [\text{C}]=3$. Checking the reaction profiles, only $2\text{A} \rightleftharpoons \text{B} + \text{C}$ yields $K_c = \frac{[\text{B}][\text{C}]}{[\text{A}]^2} = \frac{6 \times 3}{3^2} = 2$.

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