Thermodynamics and ThermochemistryhardMCQ SINGLE

An adiabatic cylinder fitted with an adiabatic piston at the right end of cylinder, is divided into Thermodynamics and Thermochemistry Chemistry Question

Question

An adiabatic cylinder fitted with an adiabatic piston at the right end of cylinder, is divided into two equal halves with a monoatomic gas on left side and diatomic gas on right side, using an impermeable movable adiabatic wall. If the piston is pushed slowly to compress the diatomic gas to $\frac{3}{4}$th of its original volume. The ratio of new volume of monoatomic gas to its initial volume would be

Answer: C

💡 Solution & Explanation

Reversible adiabatic process maintains pressure equality $P_L = P_R = P_{new}$. We have $P_0 V_0^{5/3} = P_{new} V_L^{5/3}$ and $P_0 V_0^{7/5} = P_{new} V_R^{7/5}$. Equating yields $(V_L / V_0)^{5/3} = (V_R / V_0)^{7/5}$. Since $V_R / V_0 = 3/4$, $V_L / V_0 = (3/4)^{\frac{7}{5} \times \frac{3}{5}} = (3/4)^{21/25}$.

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