Thermodynamics and ThermochemistryhardMCQ MULTIPLE

Which of the following is true for reversible adiabatic process involving an ideal gas?Thermodynamics and Thermochemistry Chemistry Question

Question

Which of the following is true for reversible adiabatic process involving an ideal gas?

Answer: D

💡 Solution & Explanation

For an adiabatic process, $P^{1-\gamma} T^\gamma = \text{const} \implies T \propto P^{1 - 1/\gamma}$. The slope $dP/dT$ depends inversely on $1 - 1/\gamma$. A higher $\gamma$ means $1 - 1/\gamma$ is larger, making the derivative $dT/dP$ larger, which structurally means $dP/dT$ (the slope on a P-T plot) is smaller in magnitude.

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