Thermodynamics and ThermochemistryhardMCQ MULTIPLE

An ideal gas is taken reversibly from state A () to the state B () along a straight line in diagram.Thermodynamics and Thermochemistry Chemistry Question

Question

An ideal gas is taken reversibly from state A ($P, V$) to the state B ($0.5 P, 2 V$) along a straight line in $PV$ diagram. Which of the following statement(s) is/are correct regarding the process?

Answer: A,B,D

💡 Solution & Explanation

The straight line equation is $P = -kV + c$. Work done is the area under the straight line, which is greater than the area under the corresponding hyperbola for an isothermal process between the same points. Since $P$ is linear in $V$, $T \propto PV \propto -kV^2 + cV$, which forms an inverted parabola in a $T-V$ plot, meaning $T$ increases to a maximum then decreases.

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