Match the column — Thermodynamics and Thermochemistry Chemistry Question

💡 Solution & Explanation

Isochoric implies constant volume, so the boundary can be rigid (P), impermeable (R), diathermal (S), insulated (T), or thermostatic (U). Isothermal operates at constant temperature, allowing rigid/non-rigid, impermeable, diathermal, and thermostatic boundaries. Isobaric must allow expansion, hence non-rigid (Q). Adiabatic forbids heat transfer, requiring insulated (T) boundaries, and can be rigid/non-rigid.