Thermodynamics and ThermochemistryhardASSERTION REASON

Read the Assertion and Reason below and choose the correct option.Thermodynamics and Thermochemistry Chemistry Question

Question

Read the Assertion and Reason below and choose the correct option.

Answer: C

💡 Solution & Explanation

Statement I correctly observes established thermochemical behaviour: fully hydrated salts and non-hydrate formers typically dissolve endothermically, while anhydrous salts that can form hydrates (e.g., anhydrous $\text{CuSO}_4$) release intense heat during the hydration step, leading to overall exothermic dissolution. Statement II provides an incorrect structural explanation; the effect is driven by the highly exothermic ion-dipole hydration interactions in the anhydrous salts, not by sheer molecular mass.

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