Thermodynamics and ThermochemistryeasyASSERTION REASON

Read the Assertion and Reason below and choose the correct option.Thermodynamics and Thermochemistry Chemistry Question

Question

Read the Assertion and Reason below and choose the correct option.

Answer: D

💡 Solution & Explanation

The temperature of an ideal gas does not *always* decrease in an adiabatic expansion; in an adiabatic free expansion against a vacuum, $W = 0$, resulting in $\Delta U = 0$ and constant temperature. Thus, Statement I is incorrect. Statement II is correct according to the first law of thermodynamics ($q = 0$, so $\Delta U = q + w = w$).

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