Redox Reactions and Volumetric AnalysishardMATCH FOLLOWING

**Match Column I with Column II (Substance vs n-factor):** <br> **Column I:** <br> (A) <br> (B) <br>Redox Reactions and Volumetric Analysis Chemistry Question

Question

**Match Column I with Column II (Substance vs n-factor):** <br> **Column I:** <br> (A) $Fe_2(C_2O_4)_3$ <br> (B) $Fe(HC_2O_4)_2$ <br> (C) $KHC_2O_4.H_2C_2O_4$ <br> (D) $Fe_{0.9}O \rightarrow Fe_2O_3$ <br> **Column II:** <br> (p) $n=6$ <br> (q) $n=5$ <br> (r) $n=4$ <br> (s) $n=0.7$

Answer: A

💡 Solution & Explanation

**Logic:** <br> (A) $Fe$ is +3 (no change). 3 oxalates lose $3 \times 2 = 6e^-$. <br> (B) $Fe^{2+} \rightarrow Fe^{3+}$ (1) and 2 oxalates lose 4. Total $n=5$. <br> (C) Reducing agent has 2 oxalate units. Total $n=4$. <br> (D) $Fe_{0.9}O$ average O.S. = 20/9. Final = 3. Change per atom = 7/9. For 0.9 atoms = $0.9 \times 7/9 = 0.7$.

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