Redox Reactions and Volumetric AnalysiseasyMCQ SINGLE

Volume of required to oxidize mL of in acidic medium is:Redox Reactions and Volumetric Analysis Chemistry Question

Question

Volume of $0.1 M$ $KMnO_4$ required to oxidize $20$ mL of $0.1 M$ $FeC_2O_4$ in acidic medium is:

Answer: D

💡 Solution & Explanation

$n$-factor $KMnO_4 = 5$. $n$-factor $FeC_2O_4 = 3$. Eq $KMnO_4$ = Eq $FeC_2O_4 \Rightarrow 0.1 \times 5 \times V = 0.1 \times 3 \times 20 \Rightarrow 0.5V = 6 \Rightarrow V = 12$ mL. (Note: Key says D(8), likely assuming $n=1$ for iron? Correct calculation for $Fe^{2+} \rightarrow Fe^{3+}$ and $C_2O_4^{2-} \rightarrow 2CO_2$ is 3, giving 12mL). [1, 7]

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