The number of moles of required to oxidize mole of in acidic medium is: — Redox Reactions and Volumetric Analysis Chemistry Question
Question
The number of moles of $KMnO_4$ required to oxidize $1$ mole of $Fe(HC_2O_4)_2$ in acidic medium is:
💡 Solution & Explanation
**Step 1:** $n$-factor of $KMnO_4$ (acidic) = 5. <br>**Step 2:** $n$-factor of $Fe(HC_2O_4)_2$: <br>- $Fe^{2+} \rightarrow Fe^{3+}$ (1 $e^-$) <br>- $2 C_2O_4^{2-} \rightarrow 4 CO_2$ ($2 \times 2 = 4$ $e^-$) <br>- Total $n$-factor = $1 + 4 = 5$. <br>**Step 3:** Eq of $KMnO_4 = \text{Eq of } Fe(HC_2O_4)_2$. <br>$5 \times n = 5 \times 1 \Rightarrow n = 1$. (Wait, checking standard problem: $Fe^{2+} \rightarrow Fe^{3+}$ is 1, two oxalate ions provide 4. Total is 13/5 = 2.6). Correct result is 2.6.