See image β GOC and Organic Chemistry Basics Chemistry Question
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π‘ Solution & Explanation
**Step 1: Identify what "electron deficiency" means** Electron deficiency refers to the positive charge density on a carbon atom. A species with maximum electron deficiency has the most electron-poor (most positive) carbon center. **Step 2: Analyze carbocation stability** All options are carbocations (positively charged carbon). Stability depends on the number of alkyl groups attached to the charged carbon: - More alkyl groups β more electron donation β more stable but *less* electron-deficient - Fewer alkyl groups β less electron donation β less stable but *more* electron-deficient **Step 3: Count alkyl groups for each carbocation** - **(A) $(CH_3)_3C^β$** β Tertiary carbocation (3 alkyl groups on CβΊ) - **(B) $CH_3\overset{β}{C}H_2$ β Primary carbocation (1 alkyl group on CβΊ) - **(C) $(CH_3)_2\overset{β}{C}H$ β Secondary carbocation (2 alkyl groups on CβΊ) - **(D) $\overset{β}{C}H_3$ β Methyl carbocation (0 alkyl groups on CβΊ) **Step 4: Determine maximum electron deficiency** The methyl cation $\overset{β}{C}H_3$ has **no alkyl groups** donating electron density to the charged carbon. This makes it the most electron-deficient species, even though it's the least stable carbocation. **Answer: (D)** β The methyl carbocation is most electron-deficient because the central carbon has minimal electron density from neighboring groups.