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In diamond, carbon atoms occupy FCC lattice points and alternate tetrahedral voids. If the edge lengSolid State Chemistry Question

Question

In diamond, carbon atoms occupy FCC lattice points and alternate tetrahedral voids. If the edge length is $356 \text{ pm}$, the radius of the carbon atom is closest to:

Answer: A

💡 Solution & Explanation

In diamond cubic structure, nearest neighbours lie along one fourth of the body diagonal, so the C-C distance is $\frac{\sqrt{3}a}{4}$. Since this equals $2r$, $r=\frac{\sqrt{3}a}{8}=\frac{1.732\times356}{8}\text{ pm}\approx77.1\text{ pm}$.

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