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The highly coordinated structure transforms into a lower coordinated -type structure upon:Solid State Chemistry Question

Question

The highly coordinated $CsCl$ structure transforms into a lower coordinated $NaCl$-type structure upon:

Answer: A

💡 Solution & Explanation

The $CsCl$ structure has coordination number $8:8$, while the $NaCl$ structure has coordination number $6:6$. $CsCl$ is known to transform to the lower-coordination $NaCl$ type on heating to about $760\text{ K}$.

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