A solid binary compound XY has the Rock Salt () structure. If the radius of the cation is exactly , β Solid State Chemistry Question
Question
A solid binary compound XY has the Rock Salt ($NaCl$) structure. If the radius of the cation $X^+$ is exactly $100 \text{ pm}$, the ideal maximum radius of the anion $Y^-$ before distortion occurs is:
Answer: B
π‘ Solution & Explanation
In the rock salt structure, the cation occupies an octahedral void, so the minimum stable ratio is $r_+/r_-=0.414$. Thus $r_- = \frac{r_+}{0.414}=\frac{100}{0.414}\text{ pm}\approx241.5\text{ pm}$.
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