Redox Reactions and Volumetric AnalysishardMCQ SINGLE⭐ Must-Do

Exactly mL of a solution is violently mixed with mL of a solution in a strictly acidic medium. WhichRedox Reactions and Volumetric Analysis Chemistry Question

Question

Exactly $10$ mL of a $0.1 M$ $KMnO_4$ solution is violently mixed with $10$ mL of a $0.1 M$ $FeSO_4$ solution in a strictly acidic medium. Which of the following statements accurately identifies the limiting reagent and correctly calculates the milli-equivalents of the unreacted species left in the final solution?

Answer: A

💡 Solution & Explanation

To determine the limiting reagent, calculate total milli-equivalents for both. Milli-equivalents of $KMnO_4 = M \times V \times n = 0.1 \times 10 \times 5 = 5.0$ meq. Milli-equivalents of $FeSO_4 = 0.1 \times 10 \times 1 = 1.0$ meq. Because $FeSO_4$ provides far fewer equivalents, it acts as the strict limiting reagent. Subtracting the reacted equivalents leaves the unreacted equivalents of $KMnO_4 = 5.0 - 1.0 = 4.0$ meq.

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