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Vulcanization radically improves the physical properties of natural rubber by heating it with sulphuPolymers Chemistry Question

Question

Vulcanization radically improves the physical properties of natural rubber by heating it with sulphur. At which specific molecular positions on the polyisoprene chains do the sulphur cross-links primarily form?

Answer: C

💡 Solution & Explanation

Sulphur stiffens the rubber by forming covalent cross-links ($-S-S-$ bridges), primarily by attacking the highly reactive allylic carbon sites adjacent to the double bonds or by adding directly across the double bonds.

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