A spirane consists of two rings sharing a single central spiro carbon. If an appropriately substitut — Isomerism and Stereochemistry Chemistry Question
Question
A spirane consists of two rings sharing a single central spiro carbon. If an appropriately substituted spirane contains exactly THREE fused rings in a continuous chain, what kind of isomerism will it actively exhibit?
Answer: A
💡 Solution & Explanation
A rigid cycloalkane ring acts mathematically identically to a $\pi$-bond. A 3-ring spirane is topologically equivalent to an odd-numbered cumulene (3 double bonds). The terminal groups are perfectly co-planar, meaning it exhibits Geometrical Isomerism but generally fails to show optical isomerism due to a plane of symmetry.
💬Ask on WhatsApp →
Still have doubts about this question?
Send it to our AI chemistry tutor on WhatsApp — gets answered in minutes