Cumulenes containing an EVEN number of consecutive double bonds (such as allenes) are stereochemical — Isomerism and Stereochemistry Chemistry Question
Question
Cumulenes containing an EVEN number of consecutive double bonds (such as allenes) are stereochemically unique. Which of the following statements accurately describes their isomeric capabilities?
Answer: B
💡 Solution & Explanation
Even-numbered cumulenes utilize mutually perpendicular unhybridized p-orbitals to form consecutive $\pi$-bonds. This forces the terminal substituents into orthogonal planes. Because the groups are $90^\circ$ apart rather than flat, they do NOT show Geometrical Isomerism (though they may show Optical Isomerism).
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