Isomerism and StereochemistryhardMCQ SINGLE⭐ Must-Do

Under the strict application of the Cahn-Ingold-Prelog (CIP) sequence rules for assigning E/Z configIsomerism and Stereochemistry Chemistry Question

Question

Under the strict application of the Cahn-Ingold-Prelog (CIP) sequence rules for assigning E/Z configurations, which of the following isotopic groups possesses the absolute highest priority?

Answer: C

💡 Solution & Explanation

CIP priority is primarily determined by atomic number. If the atoms are identical isotopes of the exact same element, CIP Rule 2 dictates that atomic mass acts as the definitive tie-breaker. Tritium (mass 3) is heavier than Deuterium (mass 2) and Hydrogen (mass 1), making the order $-T > -D > -H$.

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