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48. When a concentrated solution of a strong electrolyte is progressively diluted, its specific condElectrochemistry Chemistry Question

Question

48. When a concentrated solution of a strong electrolyte is progressively diluted, its specific conductance ($\kappa$) decreases. What is the fundamental physical reason for this?

Answer: C

💡 Solution & Explanation

Specific conductance ($\kappa$) is the conductance of exactly $1 \text{ cm}^3$ of solution. As dilution occurs, the total number of ions spreads over a much larger volume, strictly decreasing the number of ions per $1 \text{ cm}^3$, and therefore dropping $\kappa$.

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