47. An aqueous solution of Sodium Sulphate () is electrolysed using completely inert Platinum electr — Electrochemistry Chemistry Question
Question
47. An aqueous solution of Sodium Sulphate ($Na_2SO_4$) is electrolysed using completely inert Platinum electrodes. During this process, what happens to the macroscopic pH of the uniformly mixed bulk solution?
Answer: C
💡 Solution & Explanation
At the cathode, water is reduced producing $H_2$ and $OH^-$. At the anode, water is oxidised producing $O_2$ and $H^+$. Because exactly 4 equivalents of $H^+$ and $OH^-$ are generated per 4 moles of electrons, they perfectly neutralize each other in the bulk solution, leaving the pH unchanged.
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