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45. In the electrochemical mechanism of Iron rusting, what specific chemical species is reduced at tElectrochemistry Chemistry Question

Question

45. In the electrochemical mechanism of Iron rusting, what specific chemical species is reduced at the local cathodic regions on the metal surface?

Answer: D

💡 Solution & Explanation

Rusting acts as a miniature Galvanic cell. Iron metal oxidizes at the anode ($Fe \rightarrow Fe^{2+} + 2e^-$). At the cathode, dissolved atmospheric oxygen is reduced in the presence of $H^+$ (from carbonic acid or moisture) to form water: $O_2 + 4H^+ + 4e^- \rightarrow 2H_2O$.

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