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28. What is the maximum mass of sodium amalgam () formed when 500 mL of a 4.0 M aqueous solution is Electrochemistry Chemistry Question

Question

28. What is the maximum mass of sodium amalgam ($NaHg$) formed when 500 mL of a 4.0 M aqueous $NaCl$ solution is completely electrolyzed using a liquid Mercury cathode? (Atomic mass: Na=23, Hg=200)

Answer: A

💡 Solution & Explanation

500 mL of 4.0 M NaCl contains 2.0 moles of $Na^+$. On a mercury cathode, the high overvoltage of $H_2$ allows $Na^+$ to discharge, forming the amalgam $NaHg$. 2.0 moles of $Na^+$ form 2.0 moles of $NaHg$. Mass = $2.0 \times (23 + 200) = 446 g$.

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