Coordination CompoundshardMCQ SINGLE⭐ Must-Do

Synergic bonding in metal carbonyls involves -donation from CO to the metal and -back donation from Coordination Compounds Chemistry Question

Question

Synergic bonding in metal carbonyls involves $\sigma$-donation from CO to the metal and $\pi$-back donation from the metal to CO. How does this back donation uniquely affect the carbon-oxygen bond?

Answer: C

💡 Solution & Explanation

Metal-to-ligand $\pi$-back donation places electron density into the $\pi^*$ antibonding orbital of CO. This inherently weakens the C-O bond, decreasing bond order and increasing bond length [12, 59].

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