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In an octahedral field, the non-axial orbitals are shifted in energy relative to the spherical barycCoordination Compounds Chemistry Question

Question

In an octahedral field, the non-axial $t_{2g}$ orbitals are shifted in energy relative to the spherical barycentre by:

Answer: C

💡 Solution & Explanation

The $t_{2g}$ orbitals point between the approaching ligands, experiencing less repulsion, and drop below the barycentre by $-0.4 \Delta_o$ [51, 52].

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