During the Rosenmund reduction of acyl chlorides to aldehydes using gas over a Palladium catalyst, w — Aldehydes Ketones and Carboxylic Acids Chemistry Question
Question
During the Rosenmund reduction of acyl chlorides to aldehydes using $H_2$ gas over a Palladium catalyst, what is the exact function of the added Barium Sulfate ($BaSO_4$)?
Answer: C
💡 Solution & Explanation
The highly active Palladium catalyst would normally reduce the acyl chloride past the aldehyde stage to a primary alcohol. $BaSO_4$ poisons the catalyst just enough to halt the reaction safely at the aldehyde.
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