Which specific organometallic reagent is synthetically preferred to convert an acyl chloride directl — Aldehydes Ketones and Carboxylic Acids Chemistry Question
Question
Which specific organometallic reagent is synthetically preferred to convert an acyl chloride directly into a ketone, avoiding over-reaction to a tertiary alcohol?
Answer: B
💡 Solution & Explanation
Grignard reagents are too reactive and will attack the intermediate ketone to form a 3° alcohol. Dialkyl cadmium is a weaker nucleophile that reacts with the highly electrophilic acyl chloride but safely stops at the ketone.
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