Thermodynamics and ThermochemistrymediumMCQ SINGLE⭐ Must-Do

According to strict IUPAC thermochemical conventions, which of the following elemental substances poThermodynamics and Thermochemistry Chemistry Question

Question

According to strict IUPAC thermochemical conventions, which of the following elemental substances possesses a definitively non-zero standard molar enthalpy of formation ($\Delta_f H^\circ \neq 0$) at 298 K?

Answer: D

💡 Solution & Explanation

Standard states dictate $\Delta_f H^\circ = 0$ exclusively for pure elements in their most stable reference phase. Graphite and rhombic sulphur are the accepted standards. For phosphorus, highly reactive white phosphorus ($P_{white}$) is the standard, meaning $P_{red} \neq 0$.

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