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Surfactant molecules like sodium stearate form unique associated colloids (micelles) in aqueous soluSurface Chemistry Chemistry Question

Question

Surfactant molecules like sodium stearate form unique associated colloids (micelles) in aqueous solutions. Which of the following thermodynamic statements correctly defines the conditions strictly required for their spontaneous formation?

Answer: B

💡 Solution & Explanation

Surfactants act as normal strong electrolytes at low concentrations. They strictly aggregate to form protective micelles only when two critical thermodynamic thresholds are crossed simultaneously: the concentration must be above the CMC, and the temperature must be above the Kraft temperature ($T_k$).

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