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When a dilute aqueous solution of is added to a volumetric excess of dilute solution, a stable lyophSurface Chemistry Chemistry Question

Question

When a dilute aqueous solution of $AgNO_3$ is added to a volumetric excess of dilute $KI$ solution, a stable lyophobic $AgI$ sol is formed. What precise chemical structure dictates the primary electrical double layer of this sol?

Answer: C

💡 Solution & Explanation

In the presence of excess $KI$, the common iodide ion ($I^-$) is preferentially adsorbed onto the $AgI$ crystal lattice, forming a negatively charged primary layer. The highly mobile $K^+$ ions form the diffuse secondary layer in the medium, yielding the structure $[AgI] / I^- \vdots K^+$.

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