During the spontaneous adsorption of a gas on a solid surface, what are the strict thermodynamic sig — Surface Chemistry Chemistry Question
Question
During the spontaneous adsorption of a gas on a solid surface, what are the strict thermodynamic signs for the changes in Gibbs free energy ($\Delta G$), enthalpy ($\Delta H$), and entropy ($\Delta S$) respectively?
Answer: C
💡 Solution & Explanation
Adsorption restricts gas molecule movement, decreasing entropy ($\Delta S < 0$). Spontaneous processes require $\Delta G < 0$. Since $\Delta G = \Delta H - T\Delta S$, the enthalpy change ($\Delta H$) must be sufficiently negative (exothermic) to overcome the entropy penalty.
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