The compressibility factor of a real gas is given by . At temperatures significantly above the Boyle — States of Matter and Gaseous State Chemistry Question
Question
The compressibility factor $Z$ of a real gas is given by $Z = PV/nRT$. At temperatures significantly above the Boyle temperature ($T > T_B$), what is the typical behavior of $Z$ as pressure increases from zero?
Answer: D
💡 Solution & Explanation
Above the Boyle temperature, thermal energy dominates over attractive forces. Consequently, the effect of molecular size (repulsion) is the only significant deviation, causing $Z$ to be strictly greater than $1$ and increase steadily with pressure ($Z = 1 + Pb/RT$).
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