Reaction MechanismmediumMCQ SINGLE⭐ Must-Do

Which stereochemical outcome is predominantly expected when an optically active tertiary alkyl halidReaction Mechanism Chemistry Question

Question

Which stereochemical outcome is predominantly expected when an optically active tertiary alkyl halide undergoes an $S_N1$ solvolysis reaction?

Answer: C

💡 Solution & Explanation

$S_N1$ proceeds via an $sp^2$ planar carbocation. Nucleophilic attack is equally probable from both faces, yielding a nearly 50:50 racemic mixture. A slight excess of inversion occurs due to the leaving group temporarily blocking the front face (intimate ion pair).

💬
Still have doubts about this question?
Send it to our AI chemistry tutor on WhatsApp — gets answered in minutes
Ask on WhatsApp →

Practice 22,000+ questions like this

AI-adaptive practice, video lectures, and full NEET Chemistry content — all in one place.

JEE Advanced · JEE Mains · NEET · IChO · AP Chemistry