Arrange the following carbocations in decreasing order of stability: Benzyl cation (I), Allyl cation β Reaction Mechanism Chemistry Question
Question
Arrange the following carbocations in decreasing order of stability: Benzyl cation (I), Allyl cation (II), $tert$ -Butyl cation (III), Methyl cation (IV).
Answer: C
π‘ Solution & Explanation
Benzyl and Allyl cations are highly stabilized by resonance. The $tert$ -butyl cation is highly stabilized by 9 $\alpha$ -hydrogens (hyperconjugation). All three are exceptionally stable compared to the methyl cation.
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