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If an organic compound contains both Nitrogen and Sulphur, Lassaigne's fusion with a limited amount Qualitative and Quantitative Analysis Chemistry Question

Question

If an organic compound contains both Nitrogen and Sulphur, Lassaigne's fusion with a limited amount of sodium forms sodium thiocyanate ($NaSCN$). Addition of $FeCl_3$ to this extract produces:

Answer: C

💡 Solution & Explanation

The thiocyanate ion ($SCN^-$) reacts with $Fe^{3+}$ to form the ferrithiocyanate complex ($[Fe(SCN)]^{2+}$), which imparts an intense blood-red colour to the solution.

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