To correctly separate and identify Group V cations (), reagents must be added in a specific sequence — Qualitative and Quantitative Analysis Chemistry Question
Question
To correctly separate and identify Group V cations ($Ba^{2+}, Sr^{2+}, Ca^{2+}$), reagents must be added in a specific sequence. Which sequence avoids false positive precipitations?
Answer: B
💡 Solution & Explanation
Barium must be removed first as $BaCrO_4$ (yellow) because it also forms insoluble sulphates and oxalates. Then Strontium is removed as $SrSO_4$ (white). Finally, Calcium is precipitated as $CaC_2O_4$ (white).
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