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A solution containing and is treated with excess . When is passed through the resulting solution, whQualitative and Quantitative Analysis Chemistry Question

Question

A solution containing $Cu^{2+}$ and $Cd^{2+}$ is treated with excess $KCN$. When $H_2S$ is passed through the resulting solution, which of the following happens?

Answer: C

💡 Solution & Explanation

Both form soluble cyano complexes. The $[Cu(CN)_4]^{3-}$ complex is highly stable and gives no free $Cu^+$ to precipitate. The $[Cd(CN)_4]^{2-}$ complex is less stable, dissociates slightly, and allows yellow $CdS$ to precipitate.

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