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A pure aliphatic hydrocarbon undergoes complete quantitative combustion over to yield exactly of andQualitative and Quantitative Analysis Chemistry Question

Question

A pure aliphatic hydrocarbon undergoes complete quantitative combustion over $CuO$ to yield exactly $3.08 \text{ g}$ of $CO_2$ and $1.44 \text{ g}$ of $H_2O$. Assuming ideal measurement, the empirical formula of this hydrocarbon is:

Answer: B

💡 Solution & Explanation

Moles of Carbon = $3.08 \text{ g} / 44 \text{ g/mol} = 0.07 \text{ mol}$. Moles of Hydrogen atoms = $2 \times (1.44 \text{ g} / 18 \text{ g/mol}) = 0.16 \text{ mol}$. The molar ratio of $C:H$ is $0.07 : 0.16$, which normalizes to the integer ratio $7:16$. The empirical formula is thus $C_7H_{16}$.

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