The Kjeldahl method is widely used for nitrogen estimation, but it fails for specific classes of com — Qualitative and Quantitative Analysis Chemistry Question
Question
The Kjeldahl method is widely used for nitrogen estimation, but it fails for specific classes of compounds because their nitrogen cannot be quantitatively converted to ammonium sulphate. Which of the following compounds CANNOT be estimated using Kjeldahl's standard method?
Answer: D
💡 Solution & Explanation
Kjeldahl's method is fundamentally unsuited for compounds containing nitrogen in a heterocyclic ring (e.g., pyridine), or present in nitro ($-NO_2$), nitroso ($-NO$), or azo ($-N=N-$) functional groups, as these structures resist complete conversion to $(NH_4)_2SO_4$ upon digestion.
💬Ask on WhatsApp →
Still have doubts about this question?
Send it to our AI chemistry tutor on WhatsApp — gets answered in minutes