Which of the following analytical reagents yields a brilliant, specific rosy-red precipitate with io — Qualitative and Quantitative Analysis Chemistry Question
Question
Which of the following analytical reagents yields a brilliant, specific rosy-red precipitate with $Ni^{2+}$ ions exclusively in an ammoniacal (alkaline) medium?
Answer: C
💡 Solution & Explanation
DMG specifically reacts with $Ni^{2+}$ in a mildly alkaline medium (provided by $NH_4OH$) to form a stable, square planar, rosy-red complex: bis(dimethylglyoximato)nickel(II). The complex is stabilized by intramolecular hydrogen bonding.
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