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Which of the following heavy metal sulphides, obtained during systematic qualitative analysis, is prQualitative and Quantitative Analysis Chemistry Question

Question

Which of the following heavy metal sulphides, obtained during systematic qualitative analysis, is practically INSOLUBLE in boiling 50% $HNO_3$ and requires aqua regia to dissolve?

Answer: D

💡 Solution & Explanation

While the sulphides of $Cu, Pb$, and $Bi$ (Group IIA) readily dissolve in hot 50% nitric acid via oxidation of the sulphide ion to elemental sulphur, Mercury(II) sulphide ($HgS$) is exceptionally stable and requires the potent combination of oxidation and complexation provided by Aqua Regia to dissolve as $HgCl_2$.

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