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Both Sulphite () and Carbonate () anions vigorously effervesce with dilute acid, yielding colorless Qualitative and Quantitative Analysis Chemistry Question

Question

Both Sulphite ($SO_3^{2-}$) and Carbonate ($CO_3^{2-}$) anions vigorously effervesce with dilute acid, yielding colorless gases that turn lime water milky. Which specific reagent definitively and visually distinguishes a sulphite from a carbonate?

Answer: B

💡 Solution & Explanation

Both yield gases ($SO_2$ and $CO_2$) that precipitate $CaCO_3$/$CaSO_3$ with lime water. However, only $SO_2$ acts as a reducing agent strong enough to turn orange acidified $K_2Cr_2O_7$ paper green (by reducing $Cr^{6+}$ to $Cr^{3+}$).

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