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During the Dumas method for the quantitative estimation of nitrogen, the hot combustion gases are inQualitative and Quantitative Analysis Chemistry Question

Question

During the Dumas method for the quantitative estimation of nitrogen, the hot combustion gases are intentionally passed over a heated copper gauze before entering the nitrometer. What is the explicit chemical function of this heated copper gauze?

Answer: B

💡 Solution & Explanation

During the high-temperature oxidation with $CuO$, a small fraction of the organic nitrogen may be oxidized into oxides of nitrogen (e.g., $NO, NO_2$). The heated copper gauze acts as a crucial reducing agent, converting these oxides back to elemental $N_2$ gas to ensure an accurate volumetric measurement.

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